[edited] Avr-libc does not appear to support the following mcus in contrast to the avr-gcc 11.2.0 compiler documentation. There used to be avr-libc support in previous versions (regression?): ata5791, ata8210, ata8510, atmega168pb, atmega328pb, atxmega16e5
I note, there are patches amongst the open issues that bring some to life again.